Abstract
Abstract The formation of the tris(3-benzyl-triazol-5-yl)carbenium cation, a heterocyclic analogue of the trityl cation, from tris(3-benzyl-triazol-5-yl)methanol, itself generated by Cu(I)-catalyzed Huisgen reaction of benzyl azide with triethynylmethanol, in the presence of trifluoroacetic anhydride is evidenced through a selective S N 1 reactivity with various O -, N -, S -, and C -nucleophiles, giving the corresponding triazolylmethane derivatives in moderate to high yields.
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