Abstract

A. Scope and introduction B. Formation of anion radicals C. Ligand properties of anion radicals D. Formation of anion radical complexes (i) Redox reactions of complexes (ii) Coordination of “free” anion radicals (iii) Photochemical generation (iv) Thermal electron transfer between closed-shell species E. Survey of anion radical ligands and of their complexes . . , (i) Carbon ligands (ii) Nitrogen ligands (iii) Oxygen ligands (iv) Phosphorus ligands (v) Sulfur ligands F. Spectroscopy and structure (i) Magnetic resonance and magnetism (ii) Electrochemistry (iii) Electronic spectroscopy (UV/VIS/NIR) ......... (iv) Structural studies and vibrational spectroscopy ..... G. Reactivity of anion radical complexes Acknowledgements References

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