Abstract
The heat capacity and density of solutions of ammonium bromide, iodide, and nitrate in methylpyrrolidone (MP) were studied calorimetrically and densimetrically at 298.15 K. The standard partial molar heat capacities and volumes (\(\overline {C_{p_2 }^O } \) and \(\overline {V_2^O } \)) of the electrolytes in MP were calculated. The standard heat capacities \(\overline {C_{p_i }^O } \) and volumes \(\overline {V_i^O } \) of the nitrate and ammonium ions in MP were determined. The mean coordination numbers of the NH4+ and NO3− ions in a solution in MP at 298.15 K were calculated.
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