Abstract

Knowledge about thermal radiation of the atmosphere is rich in hypotheses and theories but poor in empiric evidence. Thereby, the Stefan-Boltzmann relation is of central importance in atmosphere physics, and holds the status of a natural law. However, its empirical foundation is little, tracing back to experiments made by Dulong and Petit two hundred years ago. Originated by Stefan at the end of the 19th century, and theoretically founded afterwards by Boltzmann, it delivers the absolute temperature of a blackbody—or rather of a solid opaque body (SOB)—as a result of the incident solar radiation intensity, the emitted thermal radiation of this body, and the counter-radiation of the atmosphere. Thereby, a similar character of the blackbody radiation—describable by the expression σ·T4—and the atmospheric counter-radiation was assumed. But this appears quite abstruse and must be questioned, not least since no pressure-dependency is provided. Thanks to the author’s recently published work—proposing novel measuring methods—, the possibility was opened-up not only to find an alternative approach for the counter-radiation of the atmosphere, but also to verify it by measurements. This approach was ensued from the observation that the IR-radiative emission of gases is proportional to the pressure and to the square root of the absolute temperature, which could be bolstered by applying the kinetic gas theory. The here presented verification of the modified counter-radiation term A·p·T0.5 in the Stefan-Boltzmann relation was feasible using a direct caloric method for determining the solar absorption coefficients of coloured aluminium-plates and the respective limiting temperatures under direct solar irradiation. For studying the pressure dependency, the experiments were carried out at locations with different altitudes. For the so-called atmospheric emission constant A an approximate value of 22 Wm-2 bar-1 K-0.5 was found. In the non-steady-state, the total thermal emission power of the soil is given by the difference between its blackbody radiation and the counter-radiation of the atmosphere. This relation explains to a considerable part the fact that on mountains the atmospheric temperature is lower than on lowlands, in spite of the enhanced sunlight intensity. Thereto, the so-called greenhouse gases such as carbon-dioxide do not have any influence.

Highlights

  • Thermal and IR-radiative measurements at gases encounter several principal difficulties: Firstly, gases need to be embedded in a vessel from a solid material which may considerably influence and overlay the thermal behaviour due to its higher heat capacity

  • Originated by Stefan at the end of the 19th century, and theoretically founded afterwards by Boltzmann, it delivers the absolute temperature of a blackbody—or rather of a solid opaque body (SOB)—as a result of the incident solar radiation intensity, the emitted thermal radiation of this body, and the counter-radiation of the atmosphere

  • Thanks to the author’s recently published work—proposing novel measuring methods, the possibility was opened-up to find an alternative approach for the counter-radiation of the atmosphere, and to verify it by measurements. This approach was ensued from the observation that the IR-radiative emission of gases is proportional to the pressure and to the square root of the absolute temperature, which could be bolstered by applying the kinetic gas theory

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Summary

Introduction

Thermal and IR-radiative measurements at gases encounter several principal difficulties: Firstly, gases need to be embedded in a vessel from a solid material which may considerably influence and overlay the thermal behaviour due to its higher heat capacity. Instead of this solar absorption coefficient, the complementary solar reflection coefficient αs (or the “albedo”) is used which entails its indirect determination according to the relation βs = 1 − αs Since this may lead to uncertainties due to scattering of the reflected radiation, a method for the direct determination of the solar reflection coefficient βs was developed by the author, measuring the warming-up of coloured solid opaque plates [11]. It spares you the trouble of determining the albedo and will briefly be described, in particular since it is suitable to empirically assess the Stefan-Boltzmann relation. The method for the direct determination of the solar absorption coefficient will be described, allowing the empirical verification of the proposed atmospheric term by variation of the atmospheric pressure due to different sea levels

A Novel Method Suited for the Validation of the Stefan-Boltzmann Relation
Equipment and Locations for the Present Investigation
Results, Interpretation and Conclusions

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