Abstract
Thermally induced cis— trans isomerisation is reported for square planar complexes of the type MX 2L 2, M = Pd or Pt, L = organophosphorus ligand and X = halide. However, the palladium dichloro-phenyldimethyl complex provides another example of the more unusual trans— cis isomerisation. A number of phosphine complexes of platinum have been vacuum-distilled, in some cases with accompanying isomerisation. The tendency for such isomeric behaviour is interpreted in terms of variation in metal to phosphorus bond strength.
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