Abstract

The paper presents the results of experimental studies of thermoelectrochemical systems comprising silver chloride and quinhydrone electrodes in aqueous-methanolic solutions of hydrogen, lithium, potassium, and cesium chlorides. These results and literature data are used to calculate the standard entropies of transfer of electrolytes, Soret thermal diffusion coefficients, and entropies of moving ions at 298.15 K. The influence of the nature of electrolytes and mixed solvent composition on the characteristics of thermal diffusion transfer in the systems studied is discussed.

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