The thermal behavior during the co-combustion of bituminous coal and oil palm trunk hydrochars

Abstract

ABSTRACT Utilizing oil palm trunk (OPT) residue as a co-fuel in coal-fired plants offers an environmentally favorable solution to agricultural waste disposal and fossil fuel combustion impacts. This study investigates the potential of hydrochar from OPT (HTC-OPT) as a coal-like solid fuel for co-combustion. The combustion characteristics of coal, HTC-OPT, and their blends (10–50% HTC-OPT) were analyzed via thermogravimetric analysis with heating rates ranging from 10 to 30°C/min. The Flynn-Wall-Ozawa (FWO) and Kissinger-Akahira-Sunose (KAS) models were employed to explore co-combustion interactions and kinetic parameters. Results reveal enhanced combustion efficiency with HTC-OPT addition to coal. Higher HTC-OPT ratios correlate with increased maximum combustion rates, ignition and comprehensive combustibility indices, and decreased ignition and burnout temperatures. Additionally, blended fuels exhibit a proportionally synergistic co-combustion interaction. Both KAS and FWO models indicate similar trends in activation energies, with the lowest values (49.94 kJ/mol for KAS and 60.90 kJ/mol for FWO) at a 10% HTC-OPT ratio.