Abstract

Fifty two wells have been drilled into the Broadlands-Ohaaki geothermal system, New Zealand, in the course of its development. Fluid samples collected from these wells and measured temperatures indicate that boiling is common within the East and West Bank production zones, separated at the surface by the Waikato River. Steam-heated waters form over the top of the system, above zones of boiling, and are also present on the margins of the system. They are C0 2-rich, and are responsible for dilution of the deep chloride fluids, particularly on the margins of the system. Thermal inversions are common on the margins of the system, associated with the steam-heated waters. The eastern portion of the East Bank and margins of the West Bank have cooled since peak thermal conditions, possibly due to dilution, as indicated by comparing fluid inclusion data with temperatures now present. However, fluid inclusion Th and Tm data indicate that boiling and dilution patterns similar to those now present have existedsince inclusion formation. The hydrothermal alteration of the silicic volcanics comprises an assemblage of quartz—albite—illite—adularia—calcite—chlorite—pyrite; epitode and wairakite are rare, and pyrrhotite, sphalerite and galena are generally confined to the margins of the system. Kaolin, Camontmorillonite, cristobalite and siderite are also present on the margins of the system to depths of 600–1200 m, and are related to the presence of the C0 2-rich, steam-heated waters. The deep production fluids originate from a parent (preboiled) fluid with a temperature of ∼ 300°C and CO 2 content of ∼ 0.6 mol. Excess enthalpy (i.e. two phase feed zone) discharges are not suitable for the calculation of activity ratios in the reservoir liquid and assessment of mineral—fluid equilibria; this is probably due to non-equilibrium distribution of gas species between liquid and vapor. However, an assessment of mineral—fluid equilibria is possible from the compositions of liquid feed wells. Based on these data, the reservoir fluids are now slightly undersaturated with respect to calcite and are in equilibrium with K-mica, pyrite and chlorite. The common presence of adularia and calcite in veins and open spaces may be due to a shift in mineral—fluid equilibria caused by extensive boiling and gas loss in fractures as compared to formation fluid. In contrast, the marginal steam-heated waters are in equilibrium with pyrite-pyrrhotite. Their lower pH values make them more undersaturated with respect to calcite and K-feldspar than the chloride fluids, due mainly to the lower temperatures and concentration of CO 2, resulting in interstratified illite-smectite and even kaolinite ± siderite stability. Dilution and cooling of the boiling fluids by the steam-heated waters has caused their shift to K-mica stability; the resulting deposition of illite in fractures of the East Bank may be responsible for the lower permeabilities here, causing excess enthalpy conditions. Steam-heated waters are common in geothermal systems throughout the world; recognition of dilution patterns helps in deducing the overall geochemical structure of each system. Knowledge of the distribution of steam-heated waters will also assist in locating upflow zones, and also allows their potential for casing corrosion and production-induced incursion to be assessed.

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