Abstract
The ternary system Sb–Se–V was investigated by means of powder X-ray diffraction (PXRD), differential thermal analysis (DTA) and scanning electron microscopy (SEM) in combination with electron probe microanalysis (EPMA). A special focus was set on the possible existence of misfit layer compounds (MLCs). However, none of these, other materials of low dimensionality, or bulk ternary compounds were observed in the Sb–Se–V system. The results of the evaluations in the ternary system are presented by six isothermal sections at 400 °C, 550 °C, 650 °C, 750 °C, 900 °C and 1000 °C, one solidification scheme and one Scheil's diagram.Furthermore, new results on the binary systems of Se–V, Sb–Se, and Sb–V are reported. Some alterations of the Se–V system are presented in a revised version. It comprises the elimination of the V5Se4 phase and a limitation of the thermal stability of the Se9V2 phase.
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