The temperature jump and slow evaporation in molecular gases

Abstract

We set up model transport equations that describe the behavior of molecular (diatomic and polyatomic) gases with a molecule collision rate proportional to the molecular velocity. In deriving these equations we allow for the internal (rotational) degrees of freedom, while the vibrational degrees of freedom are assumed “frozen.” We also set up an exact equation for the problem of the temperature jump with allowance for slow evaporation from the liquid surface into the saturated vapor atmosphere. Finally, we derive explicit formulas for calculating the coefficients of the temperature jump and gas-density jump above a flat surface and do the necessary numerical calculations.