Abstract

An improved electrochemical method named thermal pulse technique was designed to measure the current flowing from a potentiostatically maintained UNS S31803 electrode in 1 M NaCl solution, while various thermal pulses were applied on the solutions. Both the critical pitting temperature (CPT) and the repassivation temperature (Tr) were measured in one thermal pulse. The Tr data presented an inverted V-shape trend as the cooling rate decreased. Both the CPT and Tr values declined after multiple thermal pulses. The cyclic potentiodynamic polarization curves present a sharp transition of pitting and repassivation potential at the temperature ranged between the CPT and Tr.

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