The telltale fluorescence fingerprints of sewer flows for interpreting the low influent concentration in wastewater treatment plant

Abstract

Low degradability of wastewater treatment plant (WWTP) influents negatively affects its ability to effectively remove pollutants through wastewater treatment processes. Proactive assessment of urban sewer system performance is highly valued in the selection of targeted countermeasures for this occurrence. In this study, a fluorescence spectrum interpretation approach was developed to identify the causes of low biodegradability of WWTP influent by using parallel factor analysis (PARAFAC) and fluorescence regional integration (FRI) of excitation-emission matrix spectroscopy. Statistical analysis was also used to further interpret the PARAFAC- and FRI-derived data. The urban sewer catchment served by a WWTP in Wuhan City, China, was used as the test site to demonstrate the effectiveness of this approach. The results showed that electronics manufacturing industrial wastewater and groundwater input into the urban sewer would significantly decrease the biodegradability of the WWTP influents, and these sources were characterized by much lower fluorescence peak intensities, especially for protein-like substances, including tryptophan-like T and tyrosine-like B1 and B2. The potential conversion of high freshness T into low freshness B2 within the sewer may also contribute to this undesirable scenario. The ratio of peak T to peak B2 and the ratio of the FRI fraction of region I to that of region II can be used together to determine the predominance of industrial wastewater and groundwater. T/B2 < 1.3 indicates the entry of industrial wastewater or groundwater into urban sewers, and I/II > 0.5 further confirms the input of industrial wastewater. Accordingly, the low biodegradability of the WWTP influents in our study site is mostly due to the inflow of industrial wastewater rather than groundwater infiltration into the urban sewers. Therefore, actions should be focused on the surveillance of industrial wastewater rather than widespread sewer inspection and repairs. In this way, this methodology is cost-effective in aiding targeted countermeasures to improve the urban sewer system performance.