Abstract
A series of dimeric titanium complexes bearing salicylaldiminates, [4-R-6-tBu-2-(CH=NnBu)C6H2OTiCl2(µ-Cl)]2 [R = H (1); R = tBu (2); R = NO2 (3)], have been synthesized in high yield (>90%) by the reaction of corresponding 4-R-6-tBu-2-(CH=NnBu)C6H2OSiMe3 with TiCl4. The molecular structure of 2 has been confirmed by single-crystal X-ray diffraction analysis. When activated with methylaluminoxane, these complexes exhibit good catalytic activity for ethylene polymerization.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
