Abstract

[3,5-Bis(dialkylamino)-4 H-1,2,6-thiadiazin-4-ylidene]propanedinitriles 6a– c, react with sodium methoxide or ethoxide to give the corresponding 6-alkoxy-4-dialkylamino substituted pyrrolo[2,3- c][1,2,6]thiadiazine-5-carbonitriles 7a– f in variable yields. These new compounds are fully characterised and two rational mechanisms are proposed for their formation.

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