The synthesis of one-dimensional controllable ZnO microrods

Abstract

Various morphology ZnO submicrorods and microrods have been fabricated onto glass substrates through chemical solution growth by the source of zinc acetate (Zn(CH3COO)2.2H2O) and hexamethylene tetraamine ((CH2)6N4). We discuss the influence of PH and the concentration of the solution on the shapes of the as-synthesized ZnO samples. And analyse the growth mechanism. The regular hexagonal ZnO rods align has been made by control of a certain concentration and proper PH. The hexagonal ZnO columns mainly grew in the [002] direction. X-ray diffraction (XRD), scanning electron microscopy (SEM) and photoluminescence (PL) are used to characterize the structure, the morphology and optical property of the samples. The photoluminescence spectrum of hexagonal ZnO columns shows that there are a broad strong red band (650nm) and a broad band in short wavelength which are two overlapped emission bands with the peaks at about 380nm and 430nm.The UV emission (~387nm) comes from recombination of free excitons. The blue emission with peak at 430nm is assigned for the recombination from an electron at interstitial Zn to a hole in VB. The red emission at 650nm is ascribed to the recombination from an electron at Vo2+ to a hole in VB.