Abstract
Binuclear iron carbonyl complexes with a common aminoallyl ligand were obtained by reaction of iminoester salts [RCH=CHC(OEt)NMe 2] +BF − 4, or their tetracarbonyliron π-complexes [π-RCH=CHC(OEt)NMe 2Fe(CO) 4] +BF 4 −, with Fe 3(CO) 12. Apart from these unsaturated amides, β-aminovinylketone ethylation products [RC(OEt)CH=CHNMe 2] +BF 4 − or a mixture of the β-aminovinylketone with an alkylating agent may also be used.
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