The synthesis, light-harvesting, and photocatalysis of naphthylporphyrin-functionalized platinum nanocomposites

Abstract

A tetraphenylporphyrin bearing four naphthalene donor moieties (5,10,15,20-tetrakis(4-(naphthalen-1-ylmethoxy)phenyl)porphyrin were synthesized and characterized using 1H NMR, FTIR, UV–vis, FL, TEM, and XRD. Substituting the naphthalene groups onto the porphyrin ring led the molecule to absorb over a broader range (200–700 nm) and to undergo efficient intramolecular energy transfer from the naphthalene to the porphyrin ring. FTIR, XRD and TEM analyses indicated that within a functionalized platinum nanocomposite comprising the porphyrin, the photoreceptive dye forms a shell containing a nanosize Pt core (∼2.8 nm). The photocatalytic activity of the Pt nanocomposite towards water reduction to hydrogen was >twice that of a Pt-naphthalene-free porphyrin system. The turnover numbers (TON Pt and TON dye) and quantum yields of hydrogen ( Φ H 2 ) were 72, 7200 and 3.0%, respectively, calculated on the basis of the total amount of H 2 evolved after 12 h irradiation.