The synthesis, electrochemical and theoretical nonlinear optical properties of push–pull chromophores for photorefractive composites

Abstract

Four chromophores, of different dipole moment and polarizable anisotropy and which comprised conjugation bridges of both benzene and polyene with strong electron-donor and electron-acceptor groups, were characterized using 1H NMR, FT-IR, UV–vis, and electrochemical analyses. The electric dipole moment ( μ), polarizability ( α) and the first hyperpolarizability ( β) values of the chromophores were examined using computational methods. The contribution of orientational birefringence to total birefringence was estimated from the calculated molecular parameters of the chromophores; these parameters are important factors for predicting photorefractive efficiency.