Abstract
The tris(2-mercaptoimidazolyl)borate lead complex, [Tm Ph] 2Pb, may be synthesized by reaction of Pb(ClO 4) 2 with 2 equivalents of [Tm Ph]Li. The molecular structure of [Tm Ph] 2Pb has been determined by X–ray diffraction, revealing that it possesses an unusual structure with an inverted η 4-coordination mode for the [Tm Ph] ligand which includes a Pb···H–B interaction.
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