Abstract
Two [Formula: see text]-oxo iron(III) porphyrin complexes, [Formula: see text]-oxo-bis[meso-tetra-[Formula: see text],[Formula: see text],[Formula: see text],[Formula: see text]-([Formula: see text]-nicotina-midophenyl)porphinatoiron(III)] ([Fe(TPyPP)]2O) and its copper adduct ([Fe(TPyPP)(CuCl)]2O[CF3SO3][Formula: see text], which are derived from Gunter’s porphyrin model for cytochrome [Formula: see text]oxidase are reported. The two complexes were isolated and characterized by single crystal X-ray diffraction, UV-vis and IR spectroscopies. Crystal structural analysis including comparisons to [Formula: see text]-oxo analogues and Hirshfeld surface calculations revealed several noteworthy structural features [Formula: see text] the various picket orientations which are partially attributed to intra- and/or inter-molecular nonbonded interactions.
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