Abstract
A novel dinuclear molybdenum compound with a single sulfur bridge is reported herein. It is the first example of a dinuclear molybdenum compound containing a [Mo 20 2S] structural complex. The title compound crystallizes in a monoclinic space group P2 1/ n with the following unit cell dimensions: a= 9.281(2), b=14.712(6), c=18.699(7) Å, β= 95.10(3)°, V=2543 Å 3, Z=4, D c=1.833 g cm −3. Diffraction data of 3810 reflections with I⩾ 3σ( I) have been collected on a CAD-4 four-circle diffractometer using Mo Kα radiation. The structure has been determined by Patterson and direct methods and refined by a least-squares method to a final R index of 0.053. The structure determination shows that the angle between the molybdenum atoms MoSMo is 91.59(4)°.
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