Abstract
The triorganotin carboxylates of 2-mercapto-4-methyl-5-thiazoleacetic acid (1), R3Sn[O2CCH2- (C4H3NS)S]SnR3 (R=Me 2, n-Bu 3, Ph 4 PhCH2 5), have been synthesized and characterized by IR, 1H and 13C NMR spectroscopy. Among them, complexes 2 and 4 were also characterized by X-ray crystallography diffraction analysis, which revealed that both 2 and 4 showed a one-dimensional polymeric structure in which the geometries of the tin atoms are different: one was a distorted tetrahedron and the other was trigonal bipyramidal with the axial positions occupied by oxygen atoms.
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More From: Journal of Inorganic and Organometallic Polymers and Materials
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