Abstract
Reactions of the formamidinate ligand, RN(H)C(H)NR, L H, (R = 2,6-diisopropylphenyl), with AlMe 3, AlMe 2Cl, GaMe 3 and ZnEt 2 were investigated to examine potential coordination modes of the ligand and the effect of hydrolysis on the products. Nine new complexes have been fully characterized by X-ray crystallography and other spectroscopic techniques and highlight the diverse coordination modes of the formamidinate ligand.
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