Abstract
A new one-dimensional aluminum phosphate has been synthesized under solvothermal conditions at 180°C in the presence of 4,4′-dipyridine and the structure solved using room-temperature single-crystal X-ray diffraction data. ([C10N2H9]+[H2AlP2O8]−, Mr=376.13, triclinic, space groupP-1,a=4.9169(9) Å,b=10.696(3) Å, γ=14.660(8) Å, α=107.84(3)°, β=95.68(3)°, γ=99.91(2)°,V=713.8(1) Å3,Z=2, 1626 observed data measured with (I>3(σ(I)),R=4.56% andRw=5.42%). The structure consists of chains containing 4-membered rings of AlO4and PO4tetrahedra constituting a backbone from which hang “pendant” PO2(OH)2groups. The chains are held together by hydrogen bonding via the dipyridyl cations.
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