Abstract
In this study, a novel dioxime 10,1l-bis(hydroxyimino)-4,8,12,17-tetraaza-1,2,19,20-O-di-cyclohexylideneoctacosene (LH2) has been synthesized starting from 1,2-O-cyclohexylidene-4-aza-8-aminooctane, which has been prepared from the l-chloro-2,3-O-cyclohexylidene, and dichloroglyoxime. The structure of this vic-dioxime has been determined as the (E, Z) form according to 1H NMR, I3C NMR and IR data. Mononuclear complexes with a metal to ligand ratio of 1:2, except for UO2(VI), have been isolated with Co(III), Co(II), Cu(II) and Ni(II) salts. The metal to ligand ratio of the uranyl complex is 1:1 and it has a dimeric structure. Attempts to prepare trinuclear complexes of the ligand with Co(III), Co(II), Cu(II) and Ni(II), failed. The structure of the ligand and its complexes is proposed from elemental analyses, IR, UV-VIS, 13C and 1H NMR spectra, magnetic susceptibility measurements, thermogravimetric analyses (TGA) and differential thermal analyses (DTA).
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