The Synthesis and Application of Chitosan@Ag2O@Mn3O4 Three‐Phase Nanocomposite as a Heterogeneous Catalyst in the Synthesis of 2‐Hydroxynaphthalenepyrimidine Trione

Abstract

ABSTRACTThe catalyst is often the most expensive element in a chemical process, rather than the reactants or products. Apart from the financial benefits, it is equally crucial to recover and reuse the catalyst to prevent waste and enhance the process's greenness. This study successfully synthesized the new, superior, and recyclable heterogeneous chitosan@Ag2O@Mn3O4 three‐phase nanocatalyst with high surface area and stability using Ag2O and Mn3O4 nanoparticles that stabilized on chitosan by copreparation method and was characterized by Fourier transform infrared (FT‐IR), scanning electron microscopy (SEM), energy dispersive X‐ray (EDX), transmission electron microscopy (TEM), surface mapping (mapping), X‐ray diffraction (XRD), Brunner–Emmett–Teller (BET), thermal gravimetric analysis (TGA), and differential scanning calorimetry (DSC) techniques in detail. Following, the efficiency of the synthesized nanocatalyst in the preparation of 2‐hydroxynaphthalenepyrimidine triones using the reaction of aromatic aldehydes, β‐naphthol, and barbituric acid derivatives was investigated and proved. The advantages of this method include performing reactions at room temperature, green media, short reaction times, and the easy purification of the products.