Abstract
The reaction between aminomethanesulphonic acid, H 2NCH 2SO 3H, and phosphorus (V) chloride has been shown to yield either dimeric trichlorophosphazochloromethane, (Cl 3PNCH 2Cl) 2, or tris(chloromethyl)amine, N(CH 2Cl) 3, depending upon the mole ratio of the reactants. The latter compound is obtained in better yield as a product of the reaction of trisodium nitrilotrimethylene-sulphonate, N(CH 2SO 3Na) 3, with phosphorus (V) chloride. Certain of the physical and chemical properties of these new compounds are described.
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