Abstract
AbstractAs a promising alternative for next‐generation energy storge devices, lithium‐sulfur batteries suffer from polysulfide shuttle and the inherent slow kinetics under long‐ term operating and high mass loading which mainly cause by the absence of available immobilizer and conversion mediators. Herein, La2O3 nanoparticles anchored on graphene composite is designed and demonstrates a high‐performance sulfur immobilizer and conversion promoter. Benefiting from the composite, the corresponding Li−S batteries display good cycling stability (capacity fading rate 0.051 % per cycle after 500 cycles), high initial specific capacity (1423.7 mA h g−1 at 0.2 A g−1), and excellent cycling performance at high sulfur loading (5.03 mg cm−2). The results of experiments and density functional theoretical (DFT) calculations revealed that the La2O3 nanoparticles is a desirable separator modification material that can effectively tuning the absorption and conversion interactions with polysulfides through S−La and Li−O chemical bonds.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.