The synergistic effect of adjuvant on the intumescent flame-retardant ABS with a novel charring agent

Abstract

A laboratory-made poly-N,N′-ethyleneterephthalamide (PETA) was used as a novel charring agent and it was combined with ammonium polyphosphate (APP) to prepare the intumescent flame retardant (IFR). For improving the flame retardant efficiency of IFR on acrylonitrile–butadiene–styrene copolymer (ABS), several adjuvant (Adj), such as zeolite 4A (4A), aluminum phosphinate (AlPi), organic montmorillonite, and 2,2′-bis(2-oxazoline), was added, and the synergistic effect was investigated by the limiting oxygen index (LOI), the UL-94 (vertical flame) test, the thermogravimetric analysis (TG), and the scanning electron microscopy (SEM). The results showed that the LOI values of ABS/IFR/Adj (70/30/2) system exceeded 30, and they passed the V-0 rating in the UL-94 test. The TG data demonstrated that the thermal stability and the mass residue of ABS/IFR/Adj were effectively enhanced. Besides, the SEM indicated that adjuvant promoted the formation of the compact, uniform, dense, and intumescent charred layer after burning. After that, the synergistic effect of AlPi and 4A on APP/PETA was investigated by Thermogravimetry-Fourier transform infrared spectroscopy.