The surfactant-ionic liquid bi-functionalization of chitosan beads for their adsorption performance improvement toward Tartrazine.

Abstract

In this study, the ionic liquid (Aliquat-336) and anionic surfactant (cetyltrimethylammonium bromide, CTAB) bi-functionalized chitosan beads were prepared and characterised using different techniques, including FTIR, XRD, SEM, EDS and BET surface area analysis. The characteristic analysis confirmed the successful conjugation of chitosan beads with both surfactant and ionic liquid. The novel fabricated beads (CS-CTAB-AL) were efficiently employed, as a high-performance adsorbent, for the removal of Tartrazine (TZ), an anionic food dye, from polluted water. The optimum adsorption of TZ onto the CS-CTAB-AL was found at 2gL-1 of adsorbent in the wide pH range of 4-11, whereas just 45min was required to reach more than 90% adsorption efficiency in the studied conditions. Also, the adsorption and kinetic studies showed that the experimental data well fitted the pseudo-first-order kinetic model and the Langmuir isotherm model. The maximum adsorption capacity of prepared beads was found to be 45.95mgg-1 at 45°C. The adsorption properties of enabling CS-CTAB-AL conjugation introduced a new type of adsorbents, exploited the combination of ionic liquid and surfactant capabilities for wastewater treatment.