The surface activation of boron to improve ignition and combustion characteristic

Abstract

Boron is a very promising and highly attractive fuel because of high calorific value. However, the practical applications in explosives and propellants of boron have been limited by long ignition delay time and low combustion efficiency. Herein, nano-Al and graphene fluoride (GF) as surface activated materials are employed to coat boron (B) particles to improve ignition and combustion performance. The reaction heat of nano-Al coated B/KNO3 and GF coated B/KNO3 are 1116.83 J/g and 862.69 J/g, respectively, which are higher than that of pure B/KNO3 (823.39 J/g). The ignition delay time of B/KNO3 could be reduced through nano-Al coating. The shortest ignition delay time is only 75 ms for B coated with nano-Al of 8 wt%, which is much shorter than that of pure B/KNO3 (109 ms). However, the ignition delay time of B/KNO3 coated with GF has been increased from 109 to 187 ms. B coated with GF and nano-Al shown significantly influence on the pressure output and flame structure of B/KNO3. Furthermore, the effects of B/O ratios on the pressure output and ignition delay time have been further fully studied. For B/KNO3 coated with nano-Al and GF, the highest pressures are 88 KPa and 59 KPa for B/O ratio of 4:6, and the minimum ignition delay time are 94 ms and 148 ms for B/O ratio of 7:3. Based on the above results, the reaction process of boron coated with GF and nano-Al has been proposed to understand combustion mechanism.