Abstract
Two bands for Ar-D 2O and one band for Ar-NH 3 have been observed for the first time in the frequency region 300–500 GHz. For both complexes the bands are explained in terms of a nearly free internal rotor model, following earlier investigations of these types of complexes. We found evidence that this model is correct for Ar-D 2O. Two of the internal rotor states studied for the Ar-D 2Ocomplex show a Coriolis interaction and the interaction constant is determined. The hyperfine constants for the studied excited state of the Ar-NH 3 complex turn out to be large.
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