Abstract
The surface segregation, structure, and valence band density of states of Pt 3 Ni (100), (110), and (111) single crystals are characterized with low energy ion scattering (LEIS), low energy electron diffraction (LEED), and ultraviolet photoemission spectroscopy (UPS). The results of LEIS clearly reveal the complete surface segregation of Pt to the top layer on all crystal alloys. LEED indicates the (5 × 1) surface reconstruction on the Pt 3 Ni (100), while (110) and (111) surfaces show (2 × 1) and (1 × 1) patterns, respectively, identical to Pt single crystals. The valence bands density of states on Pt 3 Ni alloys are compared to those of Pt single crystals via UPS measurements.
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