Abstract
AbstractFor modified poly(styrene‐co‐divinylbenzene) the changes in supermolecular structure resulting from diluting the monomers during copolymerization with various amounts of inert diluents were studied. It has been found that the copolymers, obtained in the presence of substantial amounts of diluent, have a looser structure than those obtained with less diluent, as suggested by both the swelling measurements and the results of the inverse gas chromatographic (IGC) analysis. By this latter method it was found that the looser the copolymer structure, the broader was the range of adsorption‐absorption nonequilibrium region and the lower was the heat of adsorption of normal aliphatic alcohols by the copolymers. Since the copolymers had the same crosslinking degree, no difference in their apparent glass transition temperatures were detected.
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