Abstract
From a preview of proposed models a molecular one (involving neither ions nor free radicals) was chosen. The concept of scaled concentrations for intermediates is introduced. A different mechanism (involving Dushman reaction) is proposed for the ignition period.
Highlights
From a preview of proposed models a molecular one was chosen
All of them try to explain why the decomposition of oxygenated water catalyzed by iodic acid: 2. H202 HIO3/I2 2
The first step in BL modelling was to consider a redox-type switching between the iodine species based on amphoteric effect of hydrogen peroxide: 2. HIO3 + 5
Summary
From a preview of proposed models a molecular one (involving neither ions nor free radicals) was chosen. The first step in BL modelling was to consider a redox-type switching between the iodine species based on amphoteric effect of hydrogen peroxide: 2. To fix this anomaly and according to his experiments (unsaturated organic substances block the BL reaction), a six steps model involving free radicals was proposed, RES spectroscopy had not confirmed this assumption (Degn, 1967).
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