Abstract
AbstractThe vapor–liquid equilibrium (VLE) data for hydrofluorocarbons (HFCs) + hydrocarbons (HCs) and HFCs + dimethyl ether (DME) are correlated by the Soave–Redlich–Kwong, Peng–Robinson, and Carnahan–Starling–DeSantis, respectively, with one adjustable binary interaction parameter kij, and each equation can represent the satisfactory results. For the three equations, the obtained optimum interaction parameter kij is almost the same for the binaries containing the same HFC component in the same class, and when the kij of the lack‐of‐data mixtures are needed, it just needs to know the kij of any binary in the same class on the basis of the phenomena and law. Moreover, a new equation for kij is developed that enables the three equations of state to predict the VLE properties for such mixtures within reasonable accuracy. © 2015 Curtin University of Technology and John Wiley & Sons, Ltd.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
