Abstract
Abstract The equilibrium constants for the formation of silver ion complexes of various vinyl compounds in water were determined at 25°C by the distribution method. It has been found that the equilibrium constants obtained are closely related to the Hammett sigma meta values of the relevant substituents, the reaction constant being ρ=−5.07 with the correlation coefficient r=0.974. The results have been interpreted in terms of the inductive effect of the substituents as the most dominant contribution to the stabilities of these complexes.
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