Abstract
The presence of the alkoxylated intermediate formed by the addition of alcohol to the cyano group has been confirmed by the isolation of the dimeric copper(II) complex [CuCl 2C 8N 2OH 10] 2, in which each five coordinate copper atom is bound to two chlorine and two nitrogen atoms in a square planar arrangement. In addition, there are weak axial interactions between the copper and chlorine atoms which allow the formation of a centrosymmetric dimer in which the copper atom has a square planar coordination.
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