Abstract
Abstract The crystal and molecular structure of the title complex was determined by means of a single-crystal X-ray diffraction method. A crystal of Ni2C46H54N10S4, F. W. 992.67, is triclinic with a space group P\bar1, a=13.259(4), b=15.627(5), c=6.5150(16) Å, α=90.60(3), β=93.64(2), γ=112.601(19)°, U=1242.9(6) Å3, Z=1, Dm=1.32(3), Dx=1.33 Mg m−3, and μ(Mo Kα)=9.60 cm−1. The central metal atom is hexa-coordinated, being ligated with three benzylamine and two thiocyanato (SCN) nitrogen atoms as well as one SCN sulfur atom. Two metal atoms are bridged by two SCN ions; however, the Ni-S bond length is 2.639(3) Å, which is a little longer than the sum of the Shannon’s ionic radii. The distance Ni···Ni is 5.717(3) Å and the dimeric complexes are discrete in a crystal.
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