Abstract
The structure of 4-chloronortricyclene in the gas phase was determined by electron diffraction. Interatomic distances and mean square amplitudes of vibration were evaluated. The cyclopropyl ring bonds are 1.510 Å, typical of C 3 rings. A possible correlation between increased cyclopentyl bond lengths and increased flap angle is noted, as is the apparent decrease in these bond lengths with substitution of electronegative groups. A summary of CCl bond lengths in a variety of molecular environments completes the discussion.
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