Abstract
We present experimental data regarding the combined influence of hydrogen and carbon on obtaining titanium carbohydrides. For processing, the self-propagating high-temperature synthesis (SHS) technique was used. The parameters of the SHS process were established by producing two modifications for ternary phases: fcc, TiCxHy (0.43<x<1); and hcp, TiC0.38–0.41H1.12–1.20). It is shown that the addition of a Va group metal led to significant changes in structure and composition of combustion products. On the concentration triangle Ti–V–C–H the fcc carbohydride regions are separated.
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