Abstract

The influence of microstructure on the strength and fracture toughness of 18 Ni (350) maraging steel was examined. Changes in microstructure were followed by X-ray and neutron diffraction and by optical and electron microscopy. These observations have been correlated with the fracture morphology established by scanning electron microscopy. Air cooling this alloy from the austenitizing temperature results in a dislocated martensite. During the initial stage of age hardening, molybdenum atoms tend to cluster (forming preprecipitates) and the cobalt assumes short range ordered positions. Subsequent aging results in Ni3Mo and σ-FeTi with overaging being associated with the formation of equilibrium reverted austenite and Fe2Mo. The fracture behavior is examined in terms of elementary dislocation precipitate interactions. It is suggested that the development of coplanar slip in the underaged conditions leads to its increased stress corrosion susceptibility and decreased fracture toughness. The optimum aged condition is then associated with cross-slip deformation. The fracture behavior of the overaged condition is a dynamic balance between a brittle matrix and the ductile (crack blunting) reverted austenite.

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