Abstract
Three new β-diketiminatolead(II) chlorides have been synthesised, including [(BDIDMP)PbCl], [(BDIIPP)PbCl] and [(BDIPh)PbCl] (BDIDMP=[N{(2,6-Me2C6H3)C(Me)}2CH], BDIIPP=[N{(4-iPrC6H4)C(Me)}2CH] and BDIPh=[N{(C6H5)C(Me)}2CH]). Addition of sodium or potassium-alkoxide salts to [(BDIIPP)PbCl] or [(BDIPh)PbCl] resulted in the unexpected formation of bis(β-diketiminato)lead(II) complexes, [(BDIIPP)2Pb] and [(BDIPh)2Pb], whereas addition to [(BDIDMP)PbCl] led to the expected lead alkoxo complex, [(BDIDMP)PbOtBu]. The lead(II) triflate complex, [(BDIDMP)PbOTf], was synthesised by treatment of [(BDIDMP)PbCl] with AgOTf.
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