Abstract
Samarium-mediated KDN C-glycoside formation under Barbier conditions is described. The α-selectivity at C-2′ and the S-configuration of C-3″ in the C-disaccharide 15 are confirmed by empirical rules, molecular modeling and IRMA calculation based on NMR data (2D ROESY and 13C NMR).
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have