Abstract
Ensembles of beer optical absorption spectra normalized by the standard reference method (SRM) exhibit small variances, suggesting that Karhunen-Loeve (KL) principal component approximations of these spectra, using only a few coefficients, might facilitate reconstruction of the originals with enough fidelity to permit calculation of accurate tristimulus color. To test this hypothesis, the spectra of 99 beers were measured and grouped into ensembles that were used as bases for computation of KL coefficients. Approximations of spectra were reconstructed from small numbers of these coefficients. CIELAB (tristimulus) colors computed from reconstructed and original spectra were compared using CIELAB ΔE*ab as the metric. The sensitivity of color error to the form of the spectrum (transmission or absorption, normalized or not), number of coefficients, optical path length, illuminant, observer, and ensemble makeup were studied. The data and analysis indicate that accurate (ΔE*ab ≈ 1) tristimulus color can be obtained under various viewing conditions from the SRM value and 2–6 KL coefficients. Thus, SRM plus some small number of KL coefficients constitutes a full reporting of visible beer color.
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More From: Journal of the American Society of Brewing Chemists
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