The stability of Pt–Ir/C bimetallic catalysts in HI decomposition of the iodine–sulfur hydrogen production process

Abstract

Decomposition of HI is the key reaction of hydrogen production in the iodine–sulfur thermochemical water splitting cycle, so studies about the catalysts for HI decomposition have drawn increasing attention. In this study, a series of monometallic Pt/C((Pt/C-400, Pt/C-500, Pt/C-600, Pt/C-700 and Pt/C-800), Ir/C(Ir/C-400, Ir/C-500, Ir/C-600, Ir/C-700 and Ir/C-800) and bimetallic Pt–Ir catalysts supported on active carbon (Pt–Ir/C-400, Pt–Ir/C-500, Pt–Ir/C-600, Pt–Ir/C-700 and Pt–Ir/C-800 were prepared by the impregnation-reduction-calcination method. Their catalytic activities were evaluated for HI decomposition in a fixed bed reactor at 400 and 500 °C under atmospheric pressure. Their structures, metal particles size and distribution, and specific surface area were characterized by X-ray diffraction (XRD), Transmission electron microscopy (TEM) and Brunauer-Emmett-Teller (BET) surface area, respectively. The results showed that the bimetallic Pt–Ir catalyst had the excellent stability in terms of the anti-sintering structure and catalytic activity. Therefore, the bimetallic Pt–Ir catalysts are the good candidates to take the place of the traditional monometallic Pt/C catalyst for catalyzing the HI decomposition.