Abstract

Stability constants of metal-adenosine triphosphate complexes MATP 2− and MHATP −, where M is one of the divalent metal ions Cu 2+, Zn 2+, Ni 2+, Co 2+, or Mn 2+, have been obtained from pH titration data at 30 ° in 0.1 M tetramethylammonium bromide. The stabilities of these complexes follow the “ Irving-Williams sequence”, Mn 2+ < Co 2+ < Ni 2+ < Cu 2+ > Zn 2+.

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