Abstract

The d-d absorption spectra of CuL 2, where L = glycinehydroxamic acid (Glyha), l-α-alaninehydroxamic acid (Alaha), l-α-leucinehydroxamic acid (Leuha), l-histidinehydroxamic acid (Hisha) and sarcosinehydroxamic acid (Sarha), in aqueous solutions have been treated by the Angular Overlap Model (AOM) in C 2 h symmetry. Low symmetry splittings of absorption bands of the measured spectra were found by Gaussian analysis. The ligand field parameters were estimated by the Powell optimize algorithm.

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