Abstract
The following properties of the two modifications of nickel ethylmethylglyoxime have been examined: X-ray powder diffraction patterns, u.v.-vis.-i.r. solid state spectra, solubility products and intrinsic solubilities. In addition, the complex formation and chloroform distribution constants have been measured as well as the u.v.-vis. chloroform solution spectra. Differentiating properties are summarized and compared with those of nickel dimethylglyoxime. The influence of the crystal structures on the intrinsic solubilities is discussed and the distribution constants and solubilities of other nickel dialkylglyoximes are predicted.
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