Abstract

The solar eclipse of 26 February 1979 was observed from Red Lake, Canada, (52 °N, 91 °W) where totality occurred at about 1053 local time. Several research groups and government agencies participated in an extensive ground- and rocket-based observational program directed at the middle atmosphere. At the time of the eclipse, an extensive geomagnetic storm was in progress and the middle atmosphere was undergoing temperature and circulation changes associated with a stratospheric warming. Concurrent observations of atmospheric constituents, solar radiation, electron flux and other middle atmosphere parameters were obtained as inputs for a D-region predictive chemical computer code, DAIRCHEM, tailored to eclipse conditions. Ion pair production rates were computed by an E-region infrared radiance model and were used as necessary source function input values for DAIRCHEM computations. The computations yielded predictions of electron and total positive ion densities about totality. The positive ion measurements of a supersonic Gerdien condenser and a subsonic blunt probe during the eclipse were in agreement with the model computations and provided normalizing summations of total positive ions for the interpretation of mass spectrometer measurements. The chemical computer code identified principal routes for increase and removal of key species such as O 2 +, NO +, hydrated clusters and negative ions. The dominant precursor ion for pair production hydrates was O 2 + and the chemistry was characteristic of the disturbed D-region.

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